LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TOLUENE APPEARS ON NAVY LISTING OF
OCCUP CHEM REPRO HAZS. SEEK CONSULT FROM APPROP HLTH PROFESSIONALS
CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO.
ACUTE:EXCESS EXPOS TO VAPS FROM P ROD IS IRRIT TO EYES, SKIN & RESP
TRACT, MAY CAUSE FATG, WEAK, CONFUSN, HDCH, DIZZ, DROW & NUMBNESS
IN(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:LIMBS(ARMS & LEGS). VERY HIGH CONC ARE
ANESTH & MAY HAVE OTHER CNS EFTS INCLG DEATH. IRRIT OF UPPER RESP
TRACT, FATG, WEAK, DROW & HDCH. ALLERGIC/ASTHMA-TYPE RXN & DRYING
OF SKIN & DERM MAY O CCUR FOLLOWING SENSIT TO ISOCYANATES. DRYING
OF SKIN & DERM MAY OCCUR FOLLOWING PRLNGD EXPOS. TOLUENE CAN BE
(SUPDAT)
Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY AND SKIN
DISORDERS, AND PRIOR ISOCYANATE SENSITIZATION.

First Aid:INHAL:REMOVE PERS TO FRESH AIR & ADMIN ARTF RESP/O*2 AS NEC.
SKIN:IMMED WASH EXPOSED SKIN W/SOAP & H*2O. IF IRRIT
DEVELS/PERSISTS, SEEK MD ATTN. SKIN ABSORB:IMMED WASH EXPOSED SKIN
W/SOAP & H*2O. IF I RRIT DEVEL/PERSIST SEEK MD ATTN. INGEST:PROD IS
NOT INTENDED TO BE INGEST/EATEN. IF INGEST DO NOT INDUCE VOMIT.
SEEK MD ATTN. EYE:IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15-20
MINS. SEE MD.(ING 24)

Flash Point Method:CC
Flash Point:9F,-13C
Lower Limits:1.0%
Upper Limits:7.0%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, OR FOAM. DO NOT USE A
SOLID STREAM OF WATER BECAUSE IT CAN SCATTER AND SPREAD FIRE.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
EXTREMELY FLAMM LIQ & VAP. VAP MAY CAUSE FLASH FIRE. USE H*2O
SPRAY/FOG TO COOL MATL IN/NEAR FIRE.
Unusual Fire/Explosion Hazard:IF POSS MOVE BURNING MATL OUTSIDE. AVOID
INHAL OF VAPS, WHICH MAY INCL ISOCYANATES, CO, CO*2/OXIDES OF
NITROGEN. VAP MAY FORM FLAMM ATM IN CONFINED(SUPDAT)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. EVAC & VENT SPILL
AREA. DIKE SPILL AREA W/SAND, EARTH/OTHER SUITABLE ABSORB. PVNT ANY
OF MATL INTO SEWERS, H*2O SOURCES/LAND AREAS. WEAR PROT CLTHG &
RESP PROT AS REQD NIO SH/MSHA TO MAINTAIN EXPOS
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:HNDL W/NON-SPARKING TOOLS. STORE IN
COOL DRY AREA. LAUNDER CONTAMD CLTHG. KEEP OUT OF REACH OF
CHILDREN. STORE IN TIGHTLY CLSD CNTNRS TO PVNT CONTAM.
Other Precautions:KEEP AWAY FROM IGNIT SOURCES: HEAT, SPARKS, PILOT
LIGHTS, STATIC ELEC & OPEN FLAMES. VAP ARE HVR/AIR & MAY TRAVEL
ALONG GROUND TO DISTANT IGNIT SOURCES & FLASH BACK. CNTNRS EXPOSED
TO ELEV TEMPS MAY D EVEL PRESS BUILDUP & RUPTURE.(ING 18)

Respiratory Protection:USE NIOSH/MSHA APPRVD ORG VAP RESP TO PROT
AGAINST INHAL OF VAP. IF ISOCYANATE VAPS ARE PRESENT LIMS, NIOSH/MSHA APPRVD SCBA MUST BE USED. POOR WARNING PROPERTIES
OF ISOCYANATES PRECLUDE USE OF ANY AIR-PURIFYING RESP. (ING 19)
Ventilation:LOC EXHST/GENL DILUTION VENT MAY BE REQ TO MAINTAIN EXPOS
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER .
PROT EQUIP SHOULD BE PROVIDED AS NEC TO PVNT INHAL OF VAP &(ING 22)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
SPEC GRAV:0.83-0.89(H*2O=1). EXPLO HAZ:SPACES/LOW AREAS. PRESS BUILDUP
MAY OCCUR IN CLSD, HAZ CNTNRS. H*2O SPRAY/FOG SHOULD BE USED TO
KEEP CNTNRS COOL. HAZ DECOMP PROD:ALDEHYDES, ALCOHOLS & ISOCYANAT
ES. EFTS OF OVEREXP:ABSORBED BY SKIN, MUC MEMBS & EYES BY EITHER
DIRECT CONT/EXPOS TO VAPS. ABSORP MAY RSLT IN(ING 12)

Boiling Pt:B.P. Text:>151F,>66C
Vapor Pres:6.7-45.0
Vapor Density:2.0-4.0
Spec Gravity:SUPDAT
Evaporation Rate & Reference:0.7-8.3(BUTYL ACETATE =1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK OR TAN LIQUID WITH STRONG HYDROCARBON ODOR.
Percent Volatiles by Volume:75

Stability Indicator/Materials to Avoid:NO
STRONG OXIDIZERS AND REDUCING AGENTS, STRONG ACIDS AND ALKALIES.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:LOW MOLECULAR WEIGHT HYDROCARBONS,
HYDROGEN CHLORIDE, METALLIC OXIDES OF CARBON, NITROGEN & SULFUR,
ORG ACIDS, (SUPDAT)

Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS IN PERM
HAZ WASTE MGMT FACILITY. INCIN IS PREF METH OF DISP. EMPTY CNTNRS
MUST BE HNDLD W/CARE DUE TO PROD RESIDUE. DECONTAM EMPTY CNTNRS
PRIOR TO DISP. DO NOT HEAT/CUT EMPTY CNTNRS W/ELEC/GAS TORCH.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.